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Relative molecular masses in solution questions

Relative molecular masses in solution questions | form five Chemistry

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# Question
1
  1. Boiling point of a solvent is elevated by addition of a non-volatile solute. Briefly explain.
  2. Arrange the following aqueous solutions in order of increasing freezing point: 0.01 M C_{2}H_{5}OH; 0.01 M Ba_{3}(PO_{4})_{2}; 0.01 M Na_{2}SO_{4}; 0.01 M KCl ; 0.01 M Li_{3}PO_{4}. Provide clear reason(s) for the arrangement.

Short answers
2

You are provided with the following information.

Entry Value

Molar boiling point constant for benzene, K_{b}

Molar freezing point constant for benzene, K_{f}

Boiling point of benzene

Freezing point of benzene

2.53°C kg mol-1

5.12°C kg mol-1

80.1°C

5.5°C

Calculate the boling point and freezing point of a solution made by dissolving 2.40g of biphenyl,biphenyl in 75.0 g of benzene, benzeen. Show your work clearly including manipulationsof units.


Mathematical Calculation
3

An aqueous solution of urea, CO(NH_{2})_{2} at a concentration of 1.754 g dm-3 is isotonic at the same temperature with an aqueous solution of sugar at a concentration of 10.00 g dm-3 . Calculate the relative molecular mass of sugar.


Mathematical Calculation
4

Differentiate between cryoscopic constant and ebullioscopic constant.


Short answers
5

Derive an expression relating the van`t Hoff factor (​i) and the degree of dissociation (α).


Mathematical Calculation
6

Briefly, explain the effect of degree of dissociation of a solute on the boiling point of a
solution.


Mathematical Calculation
7

What mass of ethylene glycol, C​2​H​6​O2​ , the main component of antifreezing agent which must be added to a 10.0L of water to produce a solution for use in a car radiator, that freezes at -23.3oC? Assume that the density of water is exactly 1g/mL and cryoscopic constant is 1.86oC kg/mol.


Mathematical Calculation
8

A 0.120g of haemoglobin, the protein which carries oxygen in the blood was dissolved in 200cm​3 of benzene at 20oC. The solution exerted an osmotic pressure of 25.6Pa. Find the relative molecular mass of haemoglobin.


Mathematical Calculation
9

A 1% solution of sodium chloride freezes at -0.604oC. Calculate the degree of dissociation of the sodium chloride if the molal freezing point depression constant for water is 1.86oC kg/mol.


Mathematical Calculation
10

State four colligative properties useful for determination of molecular masses.


Short answers